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Chlorinated High-Purity SICL₄ for Silicon Deposition

At room temperature is a colorless liquid, volatile, strong iritant, due to hydrolysis in humid air and white acid mist, commonly used as smoke agent.
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Overview


Chlorinated High-Purity SiCL4 for Silicon Deposition is a key material in the semiconductor and solar cell manufacturing industries, primarily used for the deposition of silicon thin films. Silicon tetrachloride (SiCL4) is a chlorinated compound that, when subjected to specific chemical processes, can be decomposed to deposit high-quality silicon layers on various substrates. The high purity of SiCL4 ensures that the deposited silicon films have excellent electrical and physical properties, making it an essential component for the production of advanced semiconductor devices and efficient solar cells.


Features


High Purity: SiCL4 used for silicon deposition is manufactured with extremely high purity levels. Rigorous purification techniques are employed to remove impurities such as metals, other chlorinated compounds, and moisture. High purity is crucial as even trace amounts of impurities can degrade the quality of the deposited silicon film, affecting the performance of semiconductor devices or solar cells.

Chlorinated Composition: The chlorinated nature of SiCL4 plays a significant role in the silicon deposition process. During deposition, the chlorine atoms in SiCL4 are released, and the silicon atoms are deposited on the substrate. The chlorine can act as a reactive species, helping to control the deposition rate and the quality of the silicon film. It can also assist in removing impurities from the substrate surface during the deposition process.

Controllable Deposition Process: The silicon deposition process using SiCL4 can be precisely controlled by adjusting various process parameters, such as temperature, pressure, gas flow rates, and the presence of other reactive gases. This controllability allows for the deposition of silicon films with specific thicknesses, crystal structures, and electrical properties, tailored to the requirements of different applications.

Compatibility with Substrates: SiCL4 - based silicon deposition is compatible with a wide range of substrates, including silicon wafers, glass, and certain metals. This compatibility makes it suitable for use in different manufacturing processes, from semiconductor device fabrication to the production of thin-film solar cells.


Application


Semiconductor Device Fabrication: In semiconductor manufacturing, SiCL4 is used in chemical vapor deposition (CVD) processes to deposit silicon films on semiconductor wafers. These films can serve as epitaxial layers, which are crucial for creating high-performance transistors, integrated circuits, and other semiconductor devices. The precise control over the silicon deposition using SiCL4 enables the fabrication of devices with improved electrical characteristics and reliability.

Solar Cell Production: For solar cells, SiCL4 - based silicon deposition is used to create the active silicon layers that absorb sunlight and generate electricity. The high-quality silicon films deposited from SiCL4 can enhance the light absorption efficiency and the electrical conductivity of the solar cells, contributing to higher energy conversion rates and more efficient solar energy generation.

Microelectromechanical Systems (MEMS) Fabrication: In MEMS device manufacturing, SiCL4 can be used to deposit silicon films for creating micro - scale structures. These structures can include sensors, actuators, and other components that require precise control over the silicon layer's properties, such as thickness, stress, and electrical conductivity.


FAQ


Q: How does the chlorinated composition of SiCL4 affect the silicon deposition process?

A: The chlorine atoms in SiCL4 participate in the chemical reactions during deposition. They can act as catalysts or reactive species, influencing the decomposition of SiCL4 and the nucleation and growth of silicon on the substrate. The presence of chlorine can also help in removing surface oxides and other contaminants from the substrate, improving the quality of the deposited silicon film.

Q: What are the key factors to consider for a successful SiCL4 - based silicon deposition?

A: Key factors include maintaining high purity of SiCL4, controlling the process temperature and pressure precisely, optimizing the gas flow rates of SiCL4 and other reactive gases, and ensuring proper substrate preparation. Any deviation from these optimal conditions can result in defects or variations in the deposited silicon film, affecting the performance of the final device.

Q: Can SiCL4 be used in combination with other gases for silicon deposition?

A: Yes, SiCL4 is often used in combination with other gases, such as hydrogen and silane, in the silicon deposition process. The addition of these gases can modify the deposition rate, the crystal structure of the deposited silicon, and its electrical properties. The specific gas combination depends on the requirements of the application and the desired characteristics of the silicon film.


SICL₄


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